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Moreover, computations must be carried out with a high degree of accuracy since important parameters generally result from small differences of large numbers. Some of the electronic energy calculation techniques currently in use for perfect crystals at absolute zero of temperature will be briefly described in Section 2, then the extension to disordered systems will be discussed in Section 3. Applications to phase diagrams will be mentioned in Section 4. For reviews of the subject matter treated here the interested reader may consult Refs.